Extraction of Tin from Lead-Tin Alloy Using Vacuum Metallurgy Technology
Unlike conventional pyrometallurgical and hydrometallurgical methods, which have evolved over thousands of years, vacuum metallurgy technology has rapidly advanced since the mid-20th century. This innovative technology is utilized to extract tin from lead-tin alloys, which are co-products of secondary lead smelting processes.
Basic Process
Under vacuum conditions (ranging from 10 to 100 Pa), lead, tin, and other metals transition into liquid or vapor forms within graphite trays. In this environment, the liquid tin flows downward to a distribution tray, while the lead vapor rises, condenses, and subsequently flows downward to the same distribution tray. This distribution tray effectively directs the liquid tin and lead to separate discharge ports.

Through two or three distillation cycles, the purity of tin can reach Sn ≥ 98.5%. Meanwhile, the lead is transformed into crude lead or lead-antimony alloy. Both the purified tin and the crude lead/lead alloy can then be further refined in specialized tin or lead processing plants.

Key Equipment
The tin vacuum distillation furnace is the critical piece of equipment in this extraction process, enabling efficient separation and purification of tin from lead-tin alloys.
This advanced vacuum metallurgy technology not only enhances the extraction efficiency but also contributes to sustainable practices in metal recovery, making it an essential method in modern metallurgy.
Our tin vacuum distillation furance webpage: https://www.darnalmetaltech.com/tin-extraction/lead-tin-alloy-treatment-furnace.html